The quantum dance of oxygen

Proposal for a new phase of the element, where atoms dance in quartets

09-Jul-2014 - Italy

Perhaps not everyone knows that oxygen has quite unusually for such a simple molecule magnetic properties. The phase diagram of solid oxygen at low temperatures and high pressures shows, however, several irregularities (for example, proper "information gaps" with regard to these magnetic properties) that are still poorly understood. A team of researchers from the International School for Advanced Studies (SISSA) and International Centre for Theoretical Physics Abdus Salam (ICTP) of Trieste, while trying to understand the origin of these phenomena, have identified a new phase, in which oxygen exhibits previously unknown characteristics.

The magnetism of oxygen is related to the spin of its electrons. "In each molecule two electrons align their intrinsic spin and magnetic moment, spin 1/2, giving rise to a spin 1 magnetic moment", explains Erio Tosatti, professor at SISSA and among the authors of the paper published in PNAS. "At very high pressures, however, the world goes upside down", he jokes, "insulators become superconductors, magnetic materials lose their properties and so on. Like oxygen, for example: while exhibiting magnetic properties at intermediate pressures, oxygen molecules lose their magnetism at pressures above 80,000 atmospheres. Or at least that's what we used to think, because our studies suggest that the situation is more complex than that".

The first non-magnetic phase, called epsilon, has been studied for years. "Scientists didn't understand what was going on", continues Tosatti. "A few years ago, it became clear, first experimentally and then theoretically, that this loss of magnetism is caused by the sudden grouping of molecules into 'quartets', in turn related to some sort of 'reluctance' of oxygen to become metallic". At even higher pressures (one million atmospheres) oxygen takes on a metallic form and becomes a superconductor. "The formation of quartets with loss of magnetism could be defined as a gimmick used by oxygen to delay becoming metallic. An interesting explanation, but some inconsistencies in the epsilon-phase data at 'lower' pressures, just above 80,000 atmospheres, prompted our group to delve deeper into the matter", explains Tosatti. Tosatti, together with Michele Fabrizio from SISSA, Yanier Crespo from ICTP and Sandro Scandolo, also from ICTP, performed very delicate and extensive calculations and developed quantum models specifically to understand this corner of the phase diagram".

https://www.analytica-world.com/en/news/149062/the-quantum-dance-of-oxygen.html