In an international cooperation with partners from industry and research, physicists from the University of Vienna, together with Thorlabs, the National Institute of Standards and Technology (NIST), and the University of Kansas, have now succeeded for the first time in demonstrating high-pe ... more
Simulations Suggest Graphene Can Stretch to Be a Tunable Ion Filter
Researchers at the National Institute of Standards and Technology (NIST) have conducted simulations suggesting that graphene, in addition to its many other useful features, can be modified with special pores to act as a tunable filter or strainer for ions (charged atoms) in a liquid.
The concept, which may also work with other membrane materials, could have applications such as nanoscale mechanical sensors, drug delivery, water purification and sieves or pumps for ion mixtures similar to biological ion channels, which are critical to the function of living cells.
“Imagine something like a fine-mesh kitchen strainer with sugar flowing through it,” project leader Alex Smolyanitsky said. “You stretch that strainer in such a way that every hole in the mesh becomes 1-2 percent larger. You’d expect that the flow through that mesh will be increased by roughly the same amount. Well, here it actually increases 1,000 percent. I think that’s pretty cool, with tons of applications.”
If it can be achieved experimentally, this graphene sieve would be the first artificial ion channel offering an exponential increase in ion flow when stretched, offering possibilities for fast ion separations or pumps or precise salinity control. Collaborators plan laboratory studies of these systems, Smolyanitsky said.
Graphene is a layer of carbon atoms arranged in hexagons, similar in shape to chicken wire, that conducts electricity. The NIST molecular dynamics simulations focused on a graphene sheet 5.5 by 6.4 nanometers (nm) in size and featuring small holes lined with oxygen atoms. These pores are crown ethers—electrically neutral circular molecules known to trap metal ions. A previous NIST simulation study showed this type of graphene membrane might be used for nanofluidic computing.
In the simulations, the graphene was suspended in water containing potassium chloride, a salt that splits into potassium and chlorine ions. The crown ether pores can trap potassium ions, which have a positive charge. The trapping and release rates can be controlled electrically. An electric field of various strengths was applied to drive the ion current flowing through the membrane.
Researchers then simulated tugging on the membrane with various degrees of force to stretch and dilate the pores, greatly increasing the flow of potassium ions through the membrane. Stretching in all directions had the biggest effect, but even tugging in just one direction had a partial effect.
Researchers found that the unexpectedly large increase in ion flow was due to a subtle interplay of a number of factors, including the thinness of graphene; interactions between ions and the surrounding liquid; and the ion-pore interactions, which weaken when pores are slightly stretched. There is a very sensitive balance between ions and their surroundings, Smolyanitsky said.
- water purification
- potassium chloride
- molecular dynamics…
- ion channels
- crown ethers
Many semiconductor fabricators and research labs are under increasing pressure from, of all things, vacuum. These facilities need to remove greater amounts of gas molecules and particles from their setups as new technologies and processes demand lower and lower pressures. For example, the v ... more
Recipes for three-dimensional (3D) printing, or additive manufacturing, of parts have required as much guesswork as science. Until now. Resins and other materials that react under light to form polymers, or long chains of molecules, are attractive for 3D printing of parts ranging from arch ... more
- 1Detect neurodegenerative diseases such as Alzheimer's by a simple eye scan?
- 2Fluorescence microscopy at highest spatial and temporal resolution
- 3The Mechanics of the Immune System
- 4Resolve Biosciences Launches New Era in Single-Cell Spatial Analysis
- 5Quick look under the skin
- 6New ion trap to create the world's most accurate mass spectrometer
- 7How does your computer smell?
- 8Clocking electron movements inside an atom
- 9Sartorius closes 2020 with strong growth
- 10A clear path to better insights into biomolecules