Microfluidic platforms have revolutionized medical diagnostics in recent years. Instead of sending blood or urine samples off to a laboratory for analysis, doctors can test a single drop of a patient's blood or urine for various diseases at point-of-care without the need for expensive instr ... more
'Twist and shine': Development of a new photoluminescent sensor material
Top: The mechanophore molecule is inserted within the short, tightly packed units of the polyurethane polymer. Bottom: when a physical force (in this case stretching indicated by the symbol F) is applied onto the polymer while under an excitation source (here a UV light), the mechanophore will increase the intensity of the emitted light (here shown as Force).
Stress sensors are important tools when it comes to evaluating the robustness of a material facing strong mechanical forces. OIST researchers have just published in Advanced Materials an article reporting a new kind of sensor molecules that brightens up when the material they are incorporated into comes under heavy mechanical stress.
Such light-based sensing molecules, also called photoluminescent mechanophores, are not new, but currently available applications are single-use only. They would typically involve a strong force -- compressing, twisting or stretching for example -- breaking a specific chemical bond between two atoms or irreversibly pulling apart two molecular patterns in the sensing molecule, changing the wavelength - and thus the color - of the light emitted by the mechanophore. Once these molecules have radically changed their structure in response to this force, it is extremely difficult to return to the initial situation. While these mechanophores are useful to understand the mechanical properties of an item or a material, they do not suit well for repeated exposure to mechanical stress.
To overcome this issue, Dr. Georgy Filonenko and Prof. Julia Khusnutdinova from the Coordination Chemistry and Catalysis Unit designed a photoluminescent mechanophore that retains its properties over time and under repeated incidences of mechanical stress. The researchers incorporated the stress-sensing molecule into a common polymer material called polyurethane, widely used for everyday items from mattresses and cushions to inflatable boats, car interiors, woodworking glue and even spandex.
The scientists then stretched the resulting material with increasing force, triggering a correspondingly brighter glow under an ultraviolet light. The reaction happens within hundreds of milliseconds, resulting in a up to two-fold increase in luminescence intensity. When the mechanical traction stops, the polymer material and the mechanophore reverse to their initial position, decreasing the light readout. This is critical as it allows for repeated applications of mechanical force.
This new mechanophore is a photoluminescent compound from recently published work by Dr. Filonenko and Prof. Khusnutdinova. Despite its very simple structure the compound is extremely responsive to the physical environment which has a direct impact on the color visible with the naked eye under a UV light. These molecules were incorporated directly within the repeated patterns of the polymer material.
The high mobility of the mechanophore molecules in the polymer was found to be the key to the sensor performance. As mechanophores moved rapidly in the relaxed polymer sample, the brightness of emission was low due to these molecular motions preventing the mechanophore from emitting light. However, subjecting the material to mechanical force effectively slowed down the polymer chain motions, enabling the mechanophore to emit light more efficiently.
"Our material shows how a macroscopic force, as basic as stretching a flexible strand of material, can efficiently trigger microscopic changes all the way down to isolated molecules," commented Dr. Filonenko.
- photoluminescent me…
Ever since J.J. Thompson's 1897 discovery of the electron, scientists have attempted to describe the subatomic particle's motion using a variety of different means. Electrons are far too small and fast to be seen, even with the help of a light microscope. This has made measuring an electron ... more
Organic-inorganic perovskite materials are key components of the new generation of solar cells. Understanding properties of these materials is important for improving lifetime and quality of solar cells. Researchers from the Energy Materials and Surface Sciences (EMSS) Unit, led by Prof. Ya ... more
- 1Sartorius Campus expands: Official opening of the new manufacturing facility for laboratory instruments
- 2Liquid cats, disgust for cheese and reversed genitalia
- 3Ultrafast snapshots of relaxing electrons in solids
- 4Is the Alzheimer's gene the ring leader or the sidekick?
- 5How does a cell maintain its identity during replication?
- 6New method for identifying carbon compounds derived from fossil fuels
- 7A spectroscopic 'science camera' system for smartphones
- 8Kit will identify genetic variations without need for lab analysis
- 9New dyes detect disease through heartbeat signals
- 10Prediction of nonmetallic half-metallicity