Bacterial diseases are usually detected by first enriching samples, then separating, identifying, and counting the bacteria. This type of procedure usually takes at least two days after arrival of the sample in the laboratory. Tests that work faster, in the field, and without complex sample ... more
Biomass as a source of raw materials
New process for obtaining alkanes from bio-oil
05-19-2009: For the protection of the environment, and because of the limited amount of fossil fuels available, renewable resources, such as specially cultivated plants, wood scraps, and other plant waste, are becoming the focus of considerable attention. Processes such as pyrolysis or liquefaction allow the conversion of biomass into bio-oil, a highly promising renewable source of energy. A team of German and Chinese scientists led by Johannes A. Lercher at the Technical University of Munich has now developed a new catalytic process to convert components of bio-oil directly into alkanes and methanol. As reported in the journal Angewandte Chemie, the process is based on a "one-pot" reaction catalyzed by a precious metal on a carbon support combined with an inorganic acid.
Bio-oil is an aqueous, acidic, highly oxidized mixture. However, its high oxygen content and instability turn out to have a negative impact: bio-oil cannot be used directly as a liquid fuel. It would, however, be highly interesting as a source of basic raw materials if it were possible to convert it to alkanes. Alkanes, which are also commonly called paraffins, are saturated hydrocarbons; they are among the most important raw materials for chemical industry, and in particular as starting materials for the production of plastics. Furthermore, they are among the primary fuels in the world's economy.
Bio-oil contains a phenolic fraction consisting of compounds with the main framework being an aromatic ring made of six carbon atoms with some hydroxy (-OH) groups attached. With the new process, the phenolic components of bio-oil can be converted with high selectivity to cycloalkanes (ring-shaped alkanes) and methanol. The researchers were able to demonstrate this with various model substances. As catalyst, they used palladium metal on a carbon support, with phosphoric acid as the proton source for the reaction.
The reaction is a "one-pot" reaction, meaning a one-step reaction whose partial reactions (hydrogenation, hydrolysis, and dehydration) occur in the same reactor, with no intermediate work-up. The secret is in the catalyst, which works on all of these different reactions. The end result is a mixture of various alkanes that separates into a second phase, making it easy to separate from the aqueous bio-oil phase. The new process is a practical approach for the direct use of bio-oil for the production of alkanes.
Original publication: Johannes A. Lercher et al.; "Highly Selective Catalytic Conversion of Phenolic Bio-Oil to Alkanes"; Angewandte Chemie International Edition 2009, 48, No. 22, 4047-4050
Contact / Request information
Request further information free of charge:
Additional Information
-
News
Biomass as a source of raw materials
For the protection of the environment, and because of the limited amount of fossil fuels available, renewable resources, such as specially cultivated plants, wood scraps, and other plant waste, are becoming the focus of considerable attention. Processes such as pyrolysis or liquefaction all ... more
Diagnosis and treatment in one go: Korean researchers led by Tae Gwan Park and Jinwoo Cheon have developed the basis for a four-in-one agent that can detect, target, and disable tumor cells while also making them macroscopically and microscopically visible. As they report in the journal Ang ... more
-
News
Biomass as a source of raw materials
For the protection of the environment, and because of the limited amount of fossil fuels available, renewable resources, such as specially cultivated plants, wood scraps, and other plant waste, are becoming the focus of considerable attention. Processes such as pyrolysis or liquefaction all ... more
Diagnosis and treatment in one go: Korean researchers led by Tae Gwan Park and Jinwoo Cheon have developed the basis for a four-in-one agent that can detect, target, and disable tumor cells while also making them macroscopically and microscopically visible. As they report in the journal Ang ... more
The discovery of a soccer-ball-shaped molecule made of 60 carbon atoms was a minor revolution in chemistry: Fullerenes are spherical, highly symmetrical molecules made of carbon atoms, and are the third form of carbon after diamond and graphite. However, the C60 "soccer ball" is not the onl ... more
Arcisstrasse 21
80333 Munich
DEUTSCHLAND
- Phone
- +49-89-289-01
- Fax
- +49-89-289-22000
-
News
Large conformational changes without ATP consummation
A special group of proteins, the so-called chaperones, helps other proteins to obtain their correct conformation. Until now scientists supposed that hydrolyzing ATP provides the energy for the large conformational changes of chaperone Hsp90. Now a research team from the Nanosystems Initiati ... more
The smallest conceivable switch
For a long time miniaturization has been the magic word in electronics. Dr. Willi Auwaerter and Professor Johannes Barth, together with their team of physicists at the Technische Universitaet Muenchen (TUM), have now presented a novel molecular switch in the journal Nature Nanotechnology. D ... more
What's really in that luscious chocolate aroma?
The mouth-watering aroma of roasted cocoa beans — key ingredient for chocolate — emerges from substances that individually smell like potato chips, cooked meat, peaches, raw beef fat, cooked cabbage, human sweat, earth, cucumber, honey and an improbable palate of other distinctly un-cocoa-l ... more
- 1Sartorius grows at double-digit rates and boosts operating earnings by more than 30%
- 2Takara Bio Europe Goes Direct in 2012
- 3Thermo Fisher Scientific Awarded Patent for Cell Factory System
- 4SGS Minerals Services opens new lab in Chennai, India
- 5New analytical method for detecting the mineral oil contents in foodstuffs resulting from recycled cardboard
- 6Dunn Labortechnik celebrates its 30th anniversary
- 7Portable device will quickly detect pathogens in developing countries
- 8New technology allows scientists to watch cancer cells in action at unprecedented resolution
- 9Semiconductors for Cool Computers
- 10Guinness World Record: X-ray laser FLASH shoots fastest movie
- 1New analytical method for detecting the mineral oil contents in foodstuffs resulting from recycled cardboard
- 2Schleicher & Schuell has been purchased by Whatman plc
- 3Breakthrough in X-Ray Nanospectroscopy
- 4Agilent Technologies Completes Acquisition of BioSystem Development Business
- 5The world's fastest camera: Trillion-frame-per-second video
- 6SGS Minerals Services opens new lab in Chennai, India
- 7Danaher Announces Definitive Agreement to Acquire Leica Microsystems
- 8SCHOTT Instruments has changed its name to SI Analytics
- 9Genzyme Launches New Diagnostic Test for Common Blood Cancer
- 10Sartorius opens new plant in India
- 1The world's fastest camera: Trillion-frame-per-second video
- 2New analytical method for detecting the mineral oil contents in foodstuffs resulting from recycled cardboard
- 3Schleicher & Schuell has been purchased by Whatman plc
- 4SCHOTT Instruments has changed its name to SI Analytics
- 5Breakthrough in X-Ray Nanospectroscopy
- 6SGS Minerals Services opens new lab in Chennai, India
- 7Abbott Receives CE Mark for New Hepatitis Test
- 8Sartorius opens new plant in India
- 9Danaher Announces Definitive Agreement to Acquire Leica Microsystems
- 10Genzyme Launches New Diagnostic Test for Common Blood Cancer
- caprotec bioanalytics Announces Further Patent Protection Of Its CCMS Techno ...
- Thermo Fisher Scientific Awarded Patent for Cell Factory System
- Cost-effective Determination of Inorganic Anions and Cations in Municipal Dr ...
- Thermo Fisher Scientific Announces New Method for Low Level Detection of Vol ...
- Thermo Fisher Scientific Scientist Dr. Alexander Makarov Receives Inaugural ...
- caprotec bioanalytics Announces Further Patent Protection Of Its CCMS Technology
- Sharp images from the living mouse brain
- Katja Stolle takes over as analytica Exhibition Director
- Dr. Stefan Arnold – new CSO completes executive board of instrAction
- Sartorius grows at double-digit rates and boosts operating earnings by more than 30%
- Hamilton Robotics and French Police Scientifique Publish Paper Describing Large-Scale Production of Genetic Profiles -
- Passiermühle für Proteine - neue Methode verbessert Proteinanalyse durchschlagend -
- Olink Bioscience and Multisciences Biotech sign distributorship agreement for the Chinese market. -
- Der kleine Unterschied im Erbgut von Bakterien - - Braunschweiger Helmholtz-Forscher entwickeln Methode zur besseren Diagnose von Durchfall auslösenden Bakterien
- Proteine in 3D - - Am Max-Planck-Institut für Biophysik wird ein europaweit einmaliges "Core Center" eröffnet





